As much as I would like to see UC get an ACC invite, I don't see it coming. I think, unless the ACC makes the play to 16 teams (which is unlikely but not impossible) UC will still be in the Big East looking and hoping for the best.
I actually believe the wild card may be the Big 12. I think they will make a play to get to 12 sooner than later and may look to strike after the ACC goes to 14. I expect them to go after Florida State hard. Clemson would be on their list as well. If the Big 12 looks to expand, UC is in great shape. If FSU and Clemson go to the Big 12, I see UCF/USF, UL/UCONN and UC filling those spots in the ACC to go to 16. The ACC, out of fear of being raided again will go to 16 to be the first true mega conference. If FSU and Clemson don't leave, I see the Big 12 looking at UC and UL to go to 12. I still think BYU holds out. They could be the one to really screw UC IMO.
Of course, this realignment crap is subject to change at a moment's notice. I do feel better with the new UC President handling this, though. President Williams was WAY too married to the Big East to be proactive enough to keep UC relevant. Of course, that is pure speculation and things could have been going on behind the scenes. I believe the new President will be very proactive as he appears to be a huge UC sports fan.